Franck–Hertz experiment
1914 confirmation of the atom's quantum nature
The Franck–Hertz experiment was the first electrical measurement to clearly show the quantum nature of atoms. It was presented on 24 April 1914, to the German Physical Society in a paper by James Franck and Gustav Hertz. Franck and Hertz had designed a vacuum tube for studying energetic electrons that flew through a thin vapour of mercury atoms.
From Wikipedia, under CC BY-SA. More on occurri.